4-Chloro-N-(2,3-dimethylphenyl)benzamide
نویسندگان
چکیده
In the title compound, C(15)H(14)ClNO, the ortho- and meta-methyl substituents in the aniline ring are anti to the N-H bond. The dihedral angle between the benzoyl and aniline benzene rings is 95.0 (1)°. N-H⋯O hydrogen bonds and C-H⋯π inter-actions link the mol-ecules in the crystal structure.
منابع مشابه
2-Chloro-N-(2,3-dimethylphenyl)benzamide
In the title compound, C(15)H(14)ClNO, the N-H and C=O bonds in the amide group are anti to each other. The amide group is inclined at 60.3 (1)° to the chloro-substituted benzoyl ring and at 59.2 (1)° to the dimethyl-substituted aniline ring. The mean planes through the two benzene rings make a dihedral angle of 7.7 (1)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O ...
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The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters. The benzene and methylphenyl rings have a dihedral angle of 63.41 (5)°, while the amide group makes a dihedral angle of 20.5 ...
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The conformation of the N-H bond in the structure of the title compound, C(15)H(15)NO, is anti to the ortho and meta-methyl substituents in the aniline benzene ring, in contrast to the syn conformation observed with respect to the ortho and meta-chloro substituents in N-(2,3-dichloro-phen-yl)benzamide. Furthermore, the conformations of N-H and C=O bonds in the amide group are anti to each other...
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The conformations of the N-H and C=O bonds in the structure of the title compound, C(13)H(9)Cl(2)NO, are anti to each other, similar to that observed in N-phenyl-benzamide, N-(2-chloro-phen-yl)benzamide, N-(4-chloro-phen-yl)benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and other benzanilides. The amide -NHCO- group forms a dihedral angle of 33.0 (2)° with the b...
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In the mol-ecular structure of the title compound, C(15)H(14)ClNO, the amide group forms dihedral angles of 15.8 (2) and 27.2 (2)°, respectively, with the benzoyl and aniline rings, while the angle between the benzoyl and aniline rings is 11.5 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis.
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